There are a couple of things to be aware of in relation to printing invoices.
Why are two invoices printing?
This is a setting in Tools > Options > Other > Printers. If Printer #2 has 1 Copy highlighted, this will print to both printers. Change the setting here to 0, and only one invoice will print.
An invoice is not sending via email
This is a setting in Tools > Options > Job > Invoice. As per below, ensure that Print Invoice after invoicing a job is ticked. If not ticked, no invoice will print or be sent via email.
Further, if Printer 2 is set to print 1 copy, when emailing a hard copy will always be printed. Set this printer to 0 if a hard copy is not required.